Recursos de Química de CLC

DESCARGO DE RESPONSABILIDAD: Estos folletos proporcionan un esquema “general” del material con problemas de práctica y respuestas. Four students working on a whiteboardCada instructor puede presentar el material de manera diferente, por lo que no todo el material en los folletos puede ser cubierto por cada instructor, y algunos instructores pueden cubrir material que no está en los folletos. Por favor revise notas, diapositivas y texto en línea de su clase, y compárelos con los folletos para anotar los temas apropiados. El material para los cursos introductorios (103, 104, y 109) se carga gradualmente durante el semestre; el material para los cursos orgánicos (343 y 345) está disponible de una vez. (Nota: los materiales de Chem 109 se eliminaron en un futuro previsible).

Si encuentra un error o tiene un comentario sobre los folletos, no dude en comunicarse con Tony Jacob en atjacob@wisc.edu. Dirija sus preguntas de química a Piazza o a su asistente de enseñanza (TA).

Si desea proporcionar comentarios, hay enlaces disponibles para los recursos orgánicos todo el tiempo; para los cursos de introducción a la química, se proporcionará un enlace cerca al final del semestre. Siempre apreciamos los comentarios, así que gracias de antemano.

Aquí hay otra herramienta útil: Un calendario semestral para la primavera de 2023. De esa manera, puede agregar todas sus tareas para cada clase en los cuadros usando un bolígrafo de color diferente para cada curso.

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Química 103

Tony’s Help Sheets – Chemistry 103

Los instructores pueden presentar el contenido de manera diferente que en estos recursos;
si eso ocurre, siga siempre el contenido preferido de su instructor.

Las hojas de recursos se han eliminado con fines de edición y se publicarán antes de que comience la sesión de verano.




Química 104

Tony’s Help Sheets – Chemistry 104

Los instructores pueden presentar el contenido de manera diferente que en estos recursos;
si eso ocurre, siga siempre el contenido preferido de su instructor.

Las hojas de recursos se han eliminado con fines de edición y se publicarán antes de que comience la sesión de verano.




Química 343

Los Recursos para Química 343 de Jose


*** ¿Utiliza estos folletos de Química 343? Sus COMENTARIOS serían muy apreciados! ¡Gracias por adelantado!***
Tenga en cuenta que estos materiales de Química 343 requieren una UW NetID y una Contraseña

#1: Lewis Structures (answers) #2: Resonance Structures (answers) #3: Electron Pushing Arrows in O-Chem
#4: Alkane Nomenclature (answers) #5: Lewis Acids and Bases (answers) #6: Acid Base Practice Problems (answers)
Reactions of Alkenes-Flashcard Format
#1: Overview: Alkene Addition Reactions #2: Hydrogenation #3: Halogenation
#4: Hydration of Alkenes; Synthesis of Alcohols #5: Halohydrin Synthesis #6: Haloether Synthesis
#7: Oxymercuration-Reduction #8: Alkoxymercuration-Reduction #9: Hydroboration-oxidation
#10: Ozonolysis #11: Addition of HBr in the Presence of Peroxides #12: 1,2-Diol Formation #1
#13: 1,2-Diol Formation #2 #14: Alkene Isomerization
Addition Reactions to Alkenes Practice
Practice #1: Addition Reactions to Alkenes (answers)
Practice #2: Addition Reactions to Alkenes (answers)
Practice on Stereoisomers
#3: Practice: Stereoisomers (answers)
Practice on Cyclohexanes
#4: Practice: Cyclohexanes (answers)
Substitution (SN1 and SN2) and Elimination (E1 and E2) Reactions
Trends in Alkyl Substitution and Elimination Reactions
Practice #5: SN1, SN2 (answers)
Practice #6: Practice Questions (Mainly multiple-choice questions) (answers)
Practice #7: Practice Problems on Synthesis (answers)
Carbenes and Carbenoids-Flashcard Format
#1: Carbene and Carbenoid Reactivity
Halogenation of Alkanes-Flashcard Format
#1: Halogenation of Alkanes
Organometallics-Flashcard Format
#1: Organometallic Compounds
Alcohol Reactions-Flashcard Format
#1: Alkyl Chlorides from 1o and 2o Alcohols #2: Alkyl Bromides from 1o and 2o Alcohols #3: Alkyl Halides from 3o Alcohols
#4: Sulfonate Ester Preparation #5: Ethers from Alcohols Using Sulfonates #6: Oxidation of 1o Alcohols to Aldehydes
#7: Oxidation of 1o Alcohols to Carboxylic Acids #8: Oxidation of 2o Alcohols to Ketones #9: Rxn of 1o Alcohols with Hydrogen Halides
#10: Rxn of 2o Alcohols with Hydrogen Halides #11: Rxn of 3o Alcohols with Hydrogen Halides #12: Acid Catalyzed Dehydration of an Alcohol
Reactions of Ethers-Flashcard Format
#1: Ethers from 1o Alcohols #2: Ethers from 3o Alcohols #3: Williamson Ether Synthesis
#4: Ethers from Alkenes; Alkoxymercuration-Reduction of Alkenes #5: Rxn of Ethers with HX (1 equivalent) #6: Rxn of Ethers with Excess HX
Reactions of Epoxides-Flashcard Format
#1: Synthesis of Epoxides Using Peroxides #2: Synthesis of Epoxides Using Halohydrins #3: Acid Catalyzed Nucleophilic Reaction of an Epoxide
#4: Base-Catalyzed Nucleophilic Reaction of an Epoxide #5: Reactions of Epoxide With Organometallics
Practice on Epoxides
Practice #8: Practice Problems on Epoxide Reactivity (answers)
Synthesis and Reactions of Alkynes-Flashcard Format
#1: Synthesis of Alkynes #2: Hydrogenation of Alkynes #3: Partial Hydrogenation of Alkynes-I
#4: Partial Hydrogenation of Alkynes-II #5: Addition of 1 equivalent of HX to Alkynes #6: Addition of Excess HX to Alkynes
#7: Addition of HX in the Presence of Peroxides #8: Hydration of Alkynes #9: Hydroboration-Oxidation of Terminal Alkynes
#10: Hydroboration-Oxidation of Internal Alkynes
Alkyne Practice
Practice #9: Alkyne Reactions (answers)
Synthesis
Practice #10: Synthesis Practice (answers)
Dienes-Flashcard Format
#1: Electrophilic Addition to 1,3-Conjugated Dienes
Diels-Alder-Flashcard Format
#1: Diels-Alder Reaction
Diels-Alder Practice
Practice #11: Practice on the Diels-Alder Reaction (answers)

*** ¿Utiliza estos folletos de Chem 343? Su RETROALIMENTACIÓN sería muy apreciado! ¡Gracias por adelantado!***


Química 345

Los Recursos para Química 343 de Jose


*** ¿Utiliza estos folletos de Química 345? Sus COMENTARIOS serían muy apreciados! ¡Gracias por adelantado!***
Tenga en cuenta que estos materiales de Química 345 requieren una UW NetID y una Contraseña

1H NMR
#1: 1H NMR Spectroscopy Worksheet (answers) #2: Strategies for Solving Problems using 1H NMR, IR
IR Spectroscopy
#1: Practice Problems Ion IR Spectroscopy
(answers)
#2: More Practice Problems on IR Spectroscopy
(answers)
Electron Pushing Arrows
#1: Electron Pushing Arrows in O-Chem
Electrophilic Aromatic Substitution (EAS) – Flashcard Format
#1: EAS Nitration #2: EAS Bromination #3: EAS Chlorination
#4: EAS Sulfonation #5: EAS Friedel-Crafts Alkylation #6: EAS Friedel-Crafts Acylation
Practice #1: EAS Reactions (answers)
Benzylic and Allylic Reactions – Flashcard Format
#1: Allylic Bromination #2: Benzylic Bromination #3: Synthesis of Allylic Grignard Reagents</A
#4: Substitution Reactions #5: Elimination Reactions #6: Oxidation Reaction of Allylic and Benzylic Alcohols
Oxidation of Alkylbenzenes – Flashcard Format
#1: Oxidation of Alkylbenzene Compounds
Elimination Reactions of Vinyl Halides – Flashcard Format
#1: Alkyne Synthesis
Nucleophilic Aromatic Substitution – Flashcard Format
#1: Nucleophilic Aromatic Substitution
Reactions of Phenols – Flashcard Format
#1: Phenol Reactivity Toward Electrophilic Aromatic Substitution (EAS) #2: Reaction of Aryl Alkyl Halides with HX #3: Oxidation of Phenols
#4: Williamson Ether Synthesis
Reactions Involving Transition Metal Complexes – Flashcard Format
#1: The Heck Reaction #2: Suzuki Coupling Reaction #3: Alkene Metathesis Reaction
Aldehyde and Ketone Reactivity – Flashcard Format
#1: Aldehyde and Ketone Reduction #2: Cyanohydrin Synthesis #3: Reaction With Grignard Reagents
#4: Reaction With Acetylide Reagents #5: Acetals #6: The Base Catalyzed Formation of a Hemiacetal
#7: The Wolff-Kishner Reduction #8: The Clemmensen Reduction #9: Reaction With Primary Amines
#10: Reaction With Secondary Amines #11: The Wittig Reaction #12: The Baeyer-Villiger Reaction
#13: The Beckmann Rearrangement Reaction
Practice #2: Problems on Acetals and Synthesis (answers)
Reactivity of Carboxylic Acids and Their Derivatives – Flashcard Format
#1: Synthesis of Carboxylic Acids #2: Synthesis of Esters From Carboxylates #3: Methyl Esters by the Use of Diazomethane
#4: Fischer Esterification #5: Acid Chlorides from Carboxylic Acids #6: Transesterification
#7: Reduction of Carboxylic Acids to 1o-alcohols #8: Synthesis of Acid Anhydrides #9: Synthesis of Sulfonyl Chlorides
#10: Decarboxylation of β-Dicarboxylic Acids #11: Base Catalyzed Hydrolysis of an Amide #12: Acid Catalyzed Hydrolysis of an Amide
#13: Reaction of Esters With Grignard Reagents #14: Reaction of an Acid Chloride with a Lithium Dialkylcuprate #15: Reaction of Esters With Amines to Form Amides
#16: Hydrolysis of Acid Chlorides #17: Hydrolysis of Acid Anhydrides
#19: Base Catalyzed Lactone Hydrolysis #20: Base Catalyzed Hydrolysis of Nitriles #21: Acid Catalyzed Hydrolysis of Nitriles
#22: Acid Chloride Reactions #23: Acid Catalyzed Hydrolysis of Lactones #24: Acid Catalyzed Hydrolysis of Esters
#25: Reduction of Derivatives of Carboxylic Acid #26: Reduction of Acid Chlorides to Aldehydes #27: The Strecker Synthesis
#28: Reaction of Nitriles With Grignard Reagents
Practice #3: Problems on Carboxylic Acids and Synthesis (answers)
Reactivity of Enols, Enolate Ions and α,β-Unsaturated Carbonyl Compounds – Flashcard Format
#1: Formation of Enols Under Acidic Conditions #2: Formation of Enolate Ions Under Basic Conditions #3: The α-Halogenation of Carbonyl Compounds
#4: The Haloform Reaction #5: The Aldol Reaction Under Acidic Conditions #6: The Aldol Reaction Under Basic Conditions
#7: Halogenation of Carboxylic Acids 8: α, β-Conjugate Addition Reaction (Michael Addition) #9: 1,2 vs 1,4 Addition Reactions to α, β-Conjugate Carbonyl Compounds
#10: Claisen Condensation and Other Similar Reactions #11: The Robinson Annulation Reaction
Reactivity of Amine Compounds – Flashcard Format
#1: Direct Alkylation of Amines #2: Reactions of Amines: Acylation #3: Primary Amine Derivatives of Aldehydes and Ketones
#4: Secondary Amine Derivatives of Aldehydes and Ketones #5: Reactions of Amines: Reductive Amination (Borch Reaction) #6: Synthesis of Primary Amines (Gabriel Synthesis)
#7: Synthesis of Arylamines #8: Quaternization of Amines #9: Hofmann Elimination
#10: Electrophilic Aromatic Substitution (EAS) of Arylamines #11: Aromatic Substitution With Diazonium Salts #12: Reactions of Amines: Diazonium Salts
#13: Buchwald-Hartwig Amination #14: Curtius Rearrangement #15: Hofmann Rearrangement
#16: The Sandmeyer Reaction #17: The Mannich Reaction

*** ¿Utiliza estos folletos de Chem 343? Su RETROALIMENTACIÓN sería muy apreciado! ¡Gracias por adelantado!***