CLC Chemistry Resources

DISCLAIMER: These handouts provide a “general” outline of the material with practice problems and answers. Four students working on a whiteboardThe instructor may present the material differently, so not all of the material in the handouts maybe covered by each instructor, and some instructors may cover material not on the handouts. In addition, instructors may present the content differently; if that occurs, always follow your instructor’s preferred content. Please review your lecture notes, slides, and online text, and compare them to the handouts to note appropriate topics to work through.

If you find an error or have a comment on the handouts feel free to reach out to clc@chem.wisc.edu. Please direct your chemistry questions to Piazza or your TA.

If you wish to provide feedback, there are links available for the organic resources all the time; for the introductory chemistry courses a link near the end of the semester will be provided. We always appreciate feedback so thank you in advance!

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Chemistry 103

Tony’s Help Sheets – Chemistry 103

*** Using these Chem 103 handouts? ***
YOUR FEEDBACK WOULD BE REALLY APPRECIATED!
*** Thanks in advance! ***

Instructors may present content differently than in these resources;
if that occurs, always follow your instructor’s preferred content.


These materials are organized in units based on the Chem 103 fall/spring schedule.
The summer schedule is different. Use the appropriate materials for your Chem 103 summer schedule.
Intro to Chemistry Concepts – Module 1
Help Sheet #1
Intro
Terms, SI units, Unit Conversions, Sig Figs, Density, Periodic Table
Flashcards #1
SI Units
Print 2-sided for proper alignment
Practice Sheet #1
SI Units
Conversions with SI Units
Flashcards #2
Element Names and Symbols
First 36 elements plus a few other common ones; print 2-sided for proper alignment
Practice Sheet #2
Element Names and Symbols
Atoms, Molecules, and Ions – Module 2
Help Sheet #2
Atomic Structure
Atomic Structure, Isotopes, Average Atomic Mass, Mass Spectroscopy, Ionic versus Molecular compounds, Naming/Writing Formulas, Polyatomic Ions, Coulomb’s Law
Flashcards #3
Polyatomic Ions Formulas/Names
Print 2-sided from Adobe Reader for proper alignment
Practice Sheet #3
Monoatomic and Polyatomic Ions
Practice Sheet #4
Naming Compounds, Writing Formulas
Chemical Reactions – Module 3
Help Sheet #3
Reactions
Balancing Rxns, Types of Rxns, Writing Rxns (molecular, complete ionic, net ionic rxns); Electrolytes; Solubility Rules; Redox: Assigning oxidation numbers; What’s oxidized, reduced, oxidizing agent, reducing agent; Metal activity series
Flashcards #4
Acids and Bases/Names
Print 2-sided from Adobe Reader for proper alignment
Stoichiometry – Module 4
Help Sheet #4
Stoichiometry (Part I)
Mole calculations, Molar mass, Converting between moles/grams/molecules, Mass percent, Empirical and Molecular formulas, Finding unknown metal M
Help Sheet #5
Stoichiometry (Part II)
Reactions and mol calculations, Limiting reagents, Percent yield, Empirical formulas from combustion
Help Sheet #6
Stoichiometry (Part III)
Molarity calculations, Dilution, Solution stoichiometry (titrations); Intro to energy
Note: Solution stoichiometry (molarity) is sometimes not included on Exam 1.

Sets of practice problems to help with exam preparation
Module 1 – Practice Problems: Intro to Chem Concepts
Module 2 – Practice Problems: Atoms, molecules, and ions
Module 3 – Practice Problems: Reactions
Module 4 – Practice Problems: Stoichiometry and Energy
Note: Solution stoichiometry (molarity; HelpSheet #6) is
sometimes NOT included on Exam 1.

Gases – Module 5
Help Sheet #7
Gases (Part I)
Gas Laws, D and molar mass, STP, Stoichiometry with gases
Help Sheet #8
Gases (Part II)
Partial Pressure, Kinetic Theory of Gases, Root Mean Square Velocity, Diffusion and Effusion
Thermochemistry – Module 6
Help Sheet #9
Thermochemistry (Part I)
Terms; Work; Sign Conventions; Specific Heat Capacity; q = CmΔT; Heat Transfer; Enthalpy of a rxn, ΔHrxn°
Help Sheet #10
Thermochemistry (Part II)
Calorimetry; Phase Changes (ΔHvap°, ΔHfus°) and heating curves; Phase Change + Heat transfer; Hess’s Law; Heat of Formation (ΔHf°)
Sets of practice problems to help with exam preparation
Module 5 – Practice Problems: Gases
Module 6 – Practice Problems: Thermochemistry
Note: The beginning of Light, Matter, Atomic Structure
(HelpSheet #11; Module 7 – Practice Problems) is sometimes included on Exam 2.

Light, Matter, and Atomic Structure – Module 7
Help Sheet #11
Light, Matter, Atomic Structure
Light equations; Electromagnetic spectrum; Photoelectric effect; Quantized system and Bohr Model; Energy Level Diagram; Electron Transitions; Duality principle; de Broglie Wavelength
Note: The beginning of Light, Matter, Atomic Structure is sometimes included on Exam 2.
Help Sheet #12
Light, Matter, Atomic Structure (Part II)
Quantum: Wavefunctions; Nodes; Quantum Numbers; Orbitals Shapes; Electron Configurations: Shorthand notation; Orbital Box Diagram; Charged Transition Elements; Number of unpaired electrons
Help Sheet #13
Light, Matter, Atomic Structure (Part III)
Periodic Table Trends: Effective Nuclear Charge; Shielding; Atomic Radii, Ionization Energy, Electron Affinity; Ionic Radii
Chemical Bonding – Module 8
Help Sheet #14
Chemical Bonding
Types of bonds; Electronegativity; Bond polarity; Lewis dot structures; Resonance; Bond order; Formal charge; Bond enthalpies
Molecular Geometry – Module 9
Help Sheet #15
Molecular Geometry (Part I)
Valence Shell Electron Pair Repulsion (VSEPR); Molecular Polarity
Help Sheet #16
Molecular Geometry (Part II)
Valence Bond Theory: Hybrid Orbitals, σ and π Bonds; Geometric isomers cis/trans
Help Sheet #17
Molecular Geometry (Part III)
Molecular Orbital (MO) Theory: MO Shapes; Bond order; MO e Configuration; Molecular stability
Sometimes MO theory is skipped; skip this HelpSheet
if this topic was not covered in your lecture section.
Sets of practice problems to help with exam preparation
Module 7 – Practice Problems: Light, Matter, and Atomic Structure
Module 8 – Practice Problems: Chemical Bonding
Module 9 – Practice Problems: Molecular Geometry
Note: The beginning of Light, Matter, Atomic Structure
is sometimes included on Exam 2.

Intermolecular Forces – Module 10
Help Sheet #18
Intermolecular Forces
Liquids: Intermolecular forces; Liquid properties; Vapor pressure diagram
Phase Diagrams and Solids – Module 11
Help Sheet #19
Phase Diagrams and Solids (Part I)
Phase diagrams; Heating Curves; Clausius-Clapeyron equation
Help Sheet #20
Phase Diagrams and Solids (Part II)
Types of solids; Unit cells; Packing; Determining Empirical formulas; Coordination number; Ionic compounds; Packing efficiency; Density

More Chem 103 final exam materials will be posted a couple of weeks before the final.
WORKSHEETS to help you prepare for the Final Exam
Worksheets for Unit 1
Besides these Worksheets it’s important to work through instructor-provided
exam resources, and review the exams and quizzes from this semester
Worksheet #1 – Module 1
Intro to Chemistry Concepts

SI units; D; Terms; Periodic Table; Atomic Structure; Isotopes
Worksheet #2 – Module 2
Atoms, Molecules, and Ions

Average Atomic Mass; Mass Spectroscopy; Ionic versus Molecular compounds; Polyatomic ions; Coulomb’s Law; Naming/Writing Formulas
Worksheet #3 – Module 3
Chemical Reactions

Acids/Bases; Electrolytes; Types of Reactions; Solubility Rules; Writing Reactions (molecular, complete ion, net ionic); Assign oxidation numbers; Oxidized, Reduced, Oxidizing agents, Reducing agents; ID Redox reactions
Worksheet #4 – Module 4
Stoichiometry (Part I)

Mole calculations; Mass Percent; Empirical/Molecular Formulas from Mass%; Mass spectroscopy re-visited; Finding M
Worksheet #5 – Module 4
Stoichiometry (Part II)

Stoichiometry; Limiting Reagents; %Yield; Empirical Formulas from gCO2 and gH2O
Worksheet #6 – Module 4
Stoichiometry (Part III)

Molarity; Dilution; Solution Stoichiometry

Worksheets for Unit 2
Besides these Worksheets it’s important to work through instructor-provided
exam resources, and review the exams and quizzes from this semester
Worksheet #7 – Module 5
Gases (Part I)

Gas Laws; Stoichiometry
Worksheet #8 – Module 5
Gases (Part II)

Partial Pressure; Kinetic Molecular Theory; Velocity
Worksheet #9 – Module 6
Thermochemistry (Part I)

Terms; Work; Sign Conventions; Heat Capacity (q = CmΔT); Heat Transfer; Reaction of a enthalpy, ΔHrxn°
Worksheet #10 – Module 6
Thermochemistry (Part II)

Calorimetry; Phase changes and heating curves; Hess’s Law; ΔHf°

Worksheets for Unit 3
Besides these Worksheets it’s important to work through instructor-provided
exam resources, and review the exams and quizzes from this semester
Worksheet #11 – Module 7
Light, Matter, Electronic Structure (Part I)

Light equations; Photoelectric Effect; Bohr Model; Electron Equations/Transitions; Duality Principle; de Broglie Wavelength
Worksheet #12 – Module 7
Light, Matter, Electronic Structure (Part II)

Wavefunction; Quantum Numbers; Nodes; Orbitals; Electron Configurations
Worksheet #13 – Module 7
Light, Matter, Electronic Structure (Part III)

Effective Nuclear Charge; Periodic Table Trends: Atomic Radii; Ionization Energy; Electron Affinity; Ionic Radii
Worksheet #14 – Module 8
Chemical Bonding

Forming a Bond; Electronegativity; Types of Bonds; Bond Polarity; Lewis Dot Structures; Formal Charge; Resonance; Bond Order; Bond Enthalpy
Worksheet #15 – Module 9
Molecular Geometry (Part I)

VSEPR; 3D Images; Molecular Polarity; Geometric Isomers
Worksheet #16 – Module 9
Molecular Geometry (Part II)

Valence Bond Theory (hybrid orbitals); σ and π bonds; Orbitals That Make a Bond
Worksheet #17 – Module 9
Molecular Geometry (Part III)

Molecular Orbital (MO) Theory: MO Shapes; Bond Order; MO e Configuration; Molecular Stability

Worksheets for Post-Unit 3
Besides these Worksheets it’s important to work through instructor-provided
exam resources, and review the exams and quizzes from this semester
Worksheet #18 – Module 10
Intermolecular Forces

Intermolecular Forces; Liquid Properties; Miscibility of Liquids
Worksheet #19 – Module 11
Phase Diagrams and Solids (Part I)

Phase diagrams and heating curves; Clausius-Clapeyron equations
Worksheet #20 – Module 11
Phase Diagrams and Solids (Part II)

Types of Solids/Properties; Unit Cells; Coordination Number; Counting Atoms/Empirical Formulas; Packing Efficiency; Density

*** Using these Chem 103 handouts? ***
YOUR FEEDBACK WOULD BE REALLY APPRECIATED!
*** Thanks in advance! ***
End of the Chem 103 materials. Good luck on your finals! Have a great break!


Chemistry 104

Tony’s Help Sheets – Chemistry 104

*** Using these Chem 104 handouts? ***
YOUR FEEDBACK WOULD BE REALLY APPRECIATED!
*** Thanks in advance! ***

Instructors may present content differently than in these resources;
if that occurs, always follow your instructor’s preferred content.


These materials are organized in units based on the Chem 104 fall/spring schedule.
The summer schedule is different. Use the appropriate materials for your Chem 104 summer schedule.
Organic Chemistry – Module 12
Help Sheet #1
Chem 103 Review
Electronegativity, Lewis Dot Structures, Bond Polarity, VSEPR, Hybridization, Hybrid Orbitals used in a Bond, Intermolecular Forces, Higher Boiling Point, Solubility
Help Sheet #2
Organic (Part I)

Drawing and Naming Molecules, Functional Groups (Part I)
Practice Sheet #1
ID Functional Groups; Naming Molecules

Organic: alkanes, alkenes, alkynes, cyclic, aromatic
Help Sheet #3
Organic (Part II)

Isomers: Constitutional (also called structural); Stereoisomers: Geometric, Optical
Practice Sheet #2
Isomers
Help Sheet #4
Organic (Part III)

Functional Groups (Part II); drawing and naming
Practice Sheet #3
ID Functional Groups; Naming Molecules

Organic: alcohols, ethers, aldehydes, ketones, carboxylic acids, esters, amides, amines
Flashcards #1 – ID Functional Groups
Identifying Functional Groups
Print 2-sided with Adobe Reader for proper alignment
Help Sheet #5
Organic (Part IV)

Reactions: Ester and amide formation, ester and amide hydrolysis; Complete hydrolysis
Practice Sheet #4
Organic Reactions: Ester/amide condensation, ester/amide hydrolysis
Chemical Kinetics – Module 13
Help Sheet #6
Kinetics (Part I)
Average Rates; Initial Rates; Relative Rates; Rate Constant with Units; Evaluating a Rate Law: Initial Rates Method, Description
Help Sheet #7
Kinetics (Part II)
Evaluating a Rate Law: Integrated Rate Laws; Half Life and Half life graphs; Rate versus Concentration
Help Sheet #8
Kinetics (Part III)
Evaluating a Rate Law: Mechanisms; Reaction Coordinate Diagrams; Arrhenius Equation and Graphs
Sets of practice problems to help with exam preparation
Module 12 – Practice Problems: Organic
Module 13 – Practice Problems: Kinetics

Equilibrium – Module 14
Help Sheet #9
Equilibrium (Part I)
K Expression; Size of K; Kc versus Kp; Le Chatelier’s Principle; How K Changes as Reaction is Changed
Help Sheet #10
Equilibrium (Part II)
Equilibrium Calculations; Reaction Quotient: Q; Phase Diagrams
Acids and Bases – Module 15
Help Sheet #11
Acids and Bases (Part I)
Definitions; Conjugate A/B; Amphiprotic; Ka, Kb; Strength of A/B and Their Conjugates; Which Way does an A/B Rxn Proceed; Acidity versus Structure
Help Sheet #12
Acids and Bases (Part II)
Autoionization; pH Equations; pH Calculations for SA, SB, WA, and WB; %Ionization; Ka, Kb, pKa, pKb; Which Way does an A/B Rxn Proceed (re-visited); Polyprotic Acids; Lewis acids/bases; Spectator Ions; Salts
Sets of practice problems to help with exam preparation
Module 14 – Practice Problems: Equilibrium
Module 15 – Practice Problems: Acids and Bases

Note: Buffers (HelpSheet #13; Module 16 – Practice Problems: Buffers) or
some parts of buffers is sometimes included on Exam 2.

Aqueous Equilibria – Module 16
Help Sheet #13
Aqueous Equilibria (Part I): Buffers
ID Buffers; pH of a Buffer; Find pH of Buffer After Adding SA/SB; Buffer Range; Buffer Capacity; Buffer Preparation
Note: Buffers or some parts of buffers is sometimes included on Exam 2.
Help Sheet #14
Aqueous Equilibria (Part II): Titrations
Titration Curves: Strong Acid+Strong Base, Strong Acid+Weak Base, Weak Acid+Strong Base; Equivalence Point; Halfway to Equivalence Point; Indicators; pH Calculations of Titrations; Polyprotic Acid Titrations
Help Sheet #15
Aqueous Equilibria (Part III): Solubility
Find Ksp from Solubility; Find Solubility from Ksp; Which Solid is More Soluble?; Common Ion Effect; pH and Solubility; Does a Ppt Form?
Thermodynamics – Module 17
Help Sheet #16
Thermodynamics (Part I)
Spontaneity; Entropy, ΔS°; Pascal’s Triangle; Comparing Entropy Qualitatively; ΔSuniv°; T of a phase change; Enthalpy, ΔH° (review); Laws of Thermodynamics
Help Sheet #17
Thermodynamics (Part II)
Free Energy, ΔG°; Deriving ΔG°; ΔGf°; Signs of ΔH°, ΔS°, and ΔG°: Reaction spontaneity; T at which a reaction is spontaneous; Free Energy ΔG under non-standard conditions; G vs Extent of Reaction; Van’t Hoff equation and graph; Thermodynamics versus Kinetics
Sets of practice problems to help with exam preparation
Module 16 – Practice Problems: Aqueous Equilibria: Buffers, Titrations, Solubility (Ksp)
Module 17 – Practice Problems: Thermodynamics

Note: Buffers or some parts of buffers is sometimes included on Exam 2.

Electrochemistry – Module 18
Help Sheet #18
Electrochemistry (Part I)
Assign Oxidation Numbers; Oxidized, reduced, oxidizing/reducing agents; Balance Redox Reations; Draw Electrochemical Cells and label parts; Inert Electrodes; Line Notation; Standard Hydrogen Electrode (SHE); How E° Changes as Reaction Changes; Standard Reduction Table
Help Sheet #19
Electrochemistry (Part II)
Stronger Oxidizing/Reducing Agents; K, ΔG°, and E°; Nernst Equation; Concentration Cells; Electroylsis; Molten Systems; Types of Batteries; BAN APE

More Chem 104 final exam materials will be posted a couple of weeks before the final.
WORKSHEETS to help you prepare for the Final Exam
Worksheets for Unit 1
Besides these Worksheets it’s important to work through instructor-provided
final exam resources, and review the exams and quizzes from this semester
Worksheet #1 – Module 1
Review & Organic (Part I)

Chem 103 Review; Organic: Functional Groups and Properties; Drawing Structures; Naming
Worksheet #2 – Module 1
Organic (Part II)

Organic: Isomers
Worksheet #3 – Module 1
Organic (Part III)

Reactions: Ester Condensation and Hydrolysis, Amide Condensation and Hydrolysis; Complete Hydrolysis; Biodiesel
Worksheet #4 – Module 2
Kinetics (Part I)

Factors Affecting Rate; Rate; Avg/Initial Rate; Relative Rates; Rate Law; Units of k; Determining the Rate Law: Initial Rates Method, Description
Worksheet #5 – Module 2
Kinetics (Part II)

Integrate Rate Law equations; Determining the Rate Law: Integrate Rate Law Graphs, Half-life vs Concentration Graphs, Rates vs Concentration Graphs
Worksheet #6 – Module 2
Kinetics (Part III)

Determining the Rate Law: Mechanisms; Reaction Coordinate Diagrams; Arrhenius Equations and Plot

Worksheets for Unit 2
Besides these Worksheets it’s important to work through instructor-provided
final exam resources, and review the exams and quizzes from this semester
Worksheet #7 – Module 3
Equilibrium (Part I)

Equilibrium Expression; Size of K; Le Chatelier’s Principle; Factors Affecting Equilibrium
Worksheet #8 – Module 3
Equilibrium (Part II)

How K Changes as Rxn Changes; K Calculations; Q
Worksheet #9 – Module 4
Acids and Bases (Part I)

Identifying Acids/Bases; Strong/Weak Acids/Bases; Conjugate Acids/Bases; Water Autoionization; Amphiprotic; pH Calculations; Ka, Kb, %Ionization; Stronger Acid Weaker Conjugate Base
Worksheet #10 – Module 4
Acids and Bases (Part II)

Ka, Kb, pKa, pKb; Which Side of Rxn Favored; Acid Strength vs Structure; Spectator ions;
Polyprotic Acids; Salts; Lewis acids/bases
Worksheet #11 – Module 5
Aqueous Equilibria (Part I): Buffers

ID Buffer; Buffer pH; Add SA/SB to Buffer and Find New pH; Buffer Range/Choosing a Buffer; Buffer Preparation

Worksheets for Unit 3
Besides these Worksheets it’s important to work through instructor-provided
final exam resources, and review the exams and quizzes from this semester
Worksheet #12 – Module 5
Aqueous Equilibria (Part II): Titrations

Titration Curves; Equivalence and Halfway to Equivalence Pt; Indicators; Calculating pH During a Titration
Worksheet #13 – Module 5
Aqueous Equilibria (Part III): Solubility

Find Solubility given Ksp; Find Ksp given Solubility; Which Solid is More Soluble; Does a Precipitate Form; pH versus Solubility; Common Ion Effect; Factors Affecting Solubility
Worksheet #14 – Module 6
Thermodynamics (Part I)

Laws of Thermodynamics; Entropy; Pascal’s Triangle; Comparing Entropy Qualitatively; ΔS°univ; T of a phase change; Enthalpy; Spontaneity; ΔG°; Sign Conventions: ΔH°, ΔS°, ΔG°
Worksheet #15 – Module 6
Thermodynamics (Part II)

ΔG and ΔG°; K from ΔG°; Signs of ΔH°, ΔS°, ΔG° and Spontaneity; T when Reaction is Spontaneous; Manipulating ΔH°, ΔS°, ΔG°; Van’t Hoff Equation/Plot; G versus Extent of Reaction Graph

Worksheets for Post-Unit 3
Besides these Worksheets it’s important to work through instructor-provided
final exam resources, and review the exams and quizzes from this semester
Worksheet #16 – Module 7
Electrochemistry (Part I)

Assign Oxidation Numbers; Oxidized, reduced, oxidizing agent, reducing agent; Balance Redox Reactions; Electrochemical Cells; How E changes; Inert Electrodes; Line Notation; SHE
Worksheet #17 – Module 7
Electrochemistry (Part II)

Stronger Oxidizing/Reducing Agents; Nernst Equation; ΔG°, E°, and K; Spontaneous Reactions
Worksheet #18 – Module 7
Electrochemistry (Part III)

Concentration Cell; Electrolysis; Molten Systems; Batteries

*** Using these Chem 104 handouts? ***
YOUR FEEDBACK WOULD BE REALLY APPRECIATED!
*** Thanks in advance! ***
No more materials will be posted. Good luck on your finals! Have a great break!
 

Chemistry 343

José’s Chemistry 343 Resources

Instructors may present content differently than in these resources;
if that occurs, always follow your instructor’s preferred content.

*** Using these Chem 343 handouts? ***
YOUR FEEDBACK WOULD BE REALLY APPRECIATED!
*** Thanks in advance! ***


#1: Lewis Structures (answers) #2: Resonance Structures (answers) #3: Electron Pushing Arrows in O-Chem
#4: Alkane Nomenclature (answers) #5: Lewis Acids and Bases (answers) #6: Acid Base Practice Problems (answers)
Reactions of Alkenes-Flashcard Format
#1: Overview: Alkene Addition Reactions #2: Hydrogenation #3: Halogenation
#4: Hydration of Alkenes; Synthesis of Alcohols #5: Halohydrin Synthesis #6: Haloether Synthesis
#7: Oxymercuration-Reduction #8: Alkoxymercuration-Reduction #9: Hydroboration-oxidation
#10: Ozonolysis #11: Addition of HBr in the Presence of Peroxides #12: 1,2-Diol Formation #1
#13: 1,2-Diol Formation #2 #14: Alkene Isomerization
Addition Reactions to Alkenes Practice
Practice #1: Addition Reactions to Alkenes (answers)
Practice #2: Addition Reactions to Alkenes (answers)
Practice on Stereoisomers
Practice #3: Stereoisomers (answers)
Practice on Cyclohexanes
Practice #4: Cyclohexanes (answers)
Substitution (SN1 and SN2) and Elimination (E1 and E2) Reactions
Trends in Alkyl Substitution and Elimination Reactions
Practice #5: SN1, SN2 (answers)
Practice #6: Practice Questions (Mainly multiple-choice questions) (answers)
Practice #7: Practice Problems on Synthesis (answers)
Carbenes and Carbenoids-Flashcard Format
#1: Carbene and Carbenoid Reactivity
Halogenation of Alkanes-Flashcard Format
#1: Halogenation of Alkanes
Organometallics-Flashcard Format
#1: Organometallic Compounds
Alcohol Reactions-Flashcard Format
#1: Alkyl Chlorides from 1o and 2o Alcohols #2: Alkyl Bromides from 1o and 2o Alcohols #3: Alkyl Halides from 3o Alcohols
#4: Sulfonate Ester Preparation #5: Ethers from Alcohols Using Sulfonates #6: Oxidation of 1o Alcohols to Aldehydes
#7: Oxidation of 1o Alcohols to Carboxylic Acids #8: Oxidation of 2o Alcohols to Ketones #9: Rxn of 1o Alcohols with Hydrogen Halides
#10: Rxn of 2o Alcohols with Hydrogen Halides #11: Rxn of 3o Alcohols with Hydrogen Halides #12: Acid Catalyzed Dehydration of an Alcohol
Reactions of Ethers-Flashcard Format
#1: Ethers from 1o Alcohols #2: Ethers from 3o Alcohols #3: Williamson Ether Synthesis
#4: Ethers from Alkenes; Alkoxymercuration-Reduction of Alkenes #5: Rxn of Ethers with HX (1 equivalent) #6: Rxn of Ethers with Excess HX
Reactions of Epoxides-Flashcard Format
#1: Synthesis of Epoxides Using Peroxides #2: Synthesis of Epoxides Using Halohydrins #3: Acid Catalyzed Nucleophilic Reaction of an Epoxide
#4: Base-Catalyzed Nucleophilic Reaction of an Epoxide #5: Reactions of Epoxide With Organometallics
Practice on Epoxides
Practice #8: Practice Problems on Epoxide Reactivity (answers)
Synthesis and Reactions of Alkynes-Flashcard Format
#1: Synthesis of Alkynes #2: Hydrogenation of Alkynes #3: Partial Hydrogenation of Alkynes-I
#4: Partial Hydrogenation of Alkynes-II #5: Addition of 1 equivalent of HX to Alkynes #6: Addition of Excess HX to Alkynes
#7: Addition of HX in the Presence of Peroxides #8: Hydration of Alkynes #9: Hydroboration-Oxidation of Terminal Alkynes
#10: Hydroboration-Oxidation of Internal Alkynes
Alkyne Practice
Practice #9: Alkyne Reactions (answers)
Synthesis
Practice #10: Synthesis Practice (answers)
Dienes-Flashcard Format
#1: Electrophilic Addition to 1,3-Conjugated Dienes
Diels-Alder-Flashcard Format
#1: Diels-Alder Reaction
Diels-Alder Practice
Practice #11: Practice on the Diels-Alder Reaction (answers)

*** Using these Chem 343 handouts? Your FEEDBACK would be really appreciated! Thanks in advance! ***


Chemistry 345

José’s Chemistry 345 Resources

Instructors may present content differently than in these resources;
if that occurs, always follow your instructor’s preferred content.

*** Using these Chem 345 handouts? ***
YOUR FEEDBACK WOULD BE REALLY APPRECIATED!
*** Thanks in advance! ***


1H NMR
#1: 1H NMR Spectroscopy Worksheet (answers) #2: Strategies for Solving Problems using 1H NMR, IR
IR Spectroscopy
#1: Practice Problems Ion IR Spectroscopy
(answers)
#2: More Practice Problems on IR Spectroscopy
(answers)
Electron Pushing Arrows
#1: Electron Pushing Arrows in O-Chem
Electrophilic Aromatic Substitution (EAS) – Flashcard Format
#1: EAS Nitration #2: EAS Bromination #3: EAS Chlorination
#4: EAS Sulfonation #5: EAS Friedel-Crafts Alkylation #6: EAS Friedel-Crafts Acylation
Practice #1: EAS Reactions (answers)
Benzylic and Allylic Reactions – Flashcard Format
#1: Allylic Bromination #2: Benzylic Bromination #3: Synthesis of Allylic Grignard Reagents
#4: Substitution Reactions #5: Elimination Reactions #6: Oxidation Reaction of Allylic and Benzylic Alcohols
Oxidation of Alkylbenzenes – Flashcard Format
#1: Oxidation of Alkylbenzene Compounds
Elimination Reactions of Vinyl Halides – Flashcard Format
#1: Alkyne Synthesis
Nucleophilic Aromatic Substitution – Flashcard Format
#1: Nucleophilic Aromatic Substitution
Reactions of Phenols – Flashcard Format
#1: Phenol Reactivity Toward Electrophilic Aromatic Substitution (EAS) #2: Reaction of Aryl Alkyl Halides with HX #3: Oxidation of Phenols
#4: Williamson Ether Synthesis
Reactions Involving Transition Metal Complexes – Flashcard Format
#1: The Heck Reaction #2: Suzuki Coupling Reaction #3: Olefin Metathesis Reaction
Aldehyde and Ketone Reactivity – Flashcard Format
#1: Aldehyde and Ketone Reduction #2: Cyanohydrin Synthesis #3: Reaction With Grignard Reagents
#4: Reaction With Acetylide Reagents #5: Acetals #6: The Base Catalyzed Formation of a Hemiacetal
#7: The Wolff-Kishner Reduction #8: The Clemmensen Reduction #9: Reaction With Primary Amines
#10: Reaction With Secondary Amines #11: The Wittig Reaction #12: The Baeyer-Villiger Reaction
#13: The Beckmann Rearrangement Reaction
Practice #2: Problems on Acetals and Synthesis (answers)
Reactivity of Carboxylic Acids and Their Derivatives – Flashcard Format
#1: Synthesis of Carboxylic Acids #2: Synthesis of Esters From Carboxylates #3: Methyl Esters by the Use of Diazomethane
#4: Fischer Esterification #5: Acid Chlorides from Carboxylic Acids #6: Transesterification
#7: Reduction of Carboxylic Acids to 1o-alcohols #8: Synthesis of Acid Anhydrides #9: Synthesis of Sulfonyl Chlorides
#10: Decarboxylation of β-Dicarboxylic Acids #11: Base Catalyzed Hydrolysis of an Amide #12: Acid Catalyzed Hydrolysis of an Amide
#13: Reaction of Esters With Grignard Reagents #14: Reaction of an Acid Chloride with a Lithium Dialkylcuprate #15: Reaction of Esters With Amines to Form Amides
#16: Hydrolysis of Acid Chlorides #17: Hydrolysis of Acid Anhydrides
#19: Base Catalyzed Lactone Hydrolysis #20: Base Catalyzed Hydrolysis of Nitriles #21: Acid Catalyzed Hydrolysis of Nitriles
#22: Acid Chloride Reactions #23: Acid Catalyzed Hydrolysis of Lactones #24: Acid Catalyzed Hydrolysis of Esters
#25: Reduction of Derivatives of Carboxylic Acid #26: Reduction of Acid Chlorides to Aldehydes #27: The Strecker Synthesis
#28: Reaction of Nitriles With Grignard Reagents
Practice #3: Problems on Carboxylic Acids and Synthesis (answers)
Reactivity of Enols, Enolate Ions and α,β-Unsaturated Carbonyl Compounds – Flashcard Format
#1: Formation of Enols Under Acidic Conditions #2: Formation of Enolate Ions Under Basic Conditions #3: The α-Halogenation of Carbonyl Compounds
#4: The Haloform Reaction #5: The Aldol Reaction Under Acidic Conditions #6: The Aldol Reaction Under Basic Conditions
#7: Halogenation of Carboxylic Acids #8: α, β-Conjugate Addition Reaction (Michael Addition) #9: 1,2 vs 1,4 Addition Reactions to α, β-Conjugate Carbonyl Compounds
#10: Claisen Condensation and Other Similar Reactions #11: The Robinson Annulation Reaction
Reactivity of Amine Compounds – Flashcard Format
#1: Direct Alkylation of Amines #2: Reactions of Amines: Acylation #3: Primary Amine Derivatives of Aldehydes and Ketones
#4: Secondary Amine Derivatives of Aldehydes and Ketones #5: Reactions of Amines: Reductive Amination (Borch Reaction) #6: Synthesis of Primary Amines (Gabriel Synthesis)
#7: Synthesis of Arylamines #8: Quaternization of Amines #9: Hofmann Elimination
#10: Electrophilic Aromatic Substitution (EAS) of Arylamines #11: Aromatic Substitution With Diazonium Salts #12: Reactions of Amines: Diazonium Salts
#13: Buchwald-Hartwig Amination #14: Curtius Rearrangement #15: Hofmann Rearrangement
#16: The Sandmeyer Reaction #17: The Mannich Reaction

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